بوتیل هیدروکسی تولوئن 817074 مرک Butylhydroxytoluene 817074 merck
بوتیل هیدروکسی تولوئن 817074 مرک
Butylhydroxytoluene 817074 merck
Butylhydroxytoluene Ph Eur,JPE,NF,E 321
Product Information
CAS number 128-37-0
EC number 204-881-4
Grade Ph Eur,JPE,NF,E 321
Hill Formula C₁₅H₂₄O
Molar Mass 220.35g/mol
HS Code 2907 19 90
Structure formula Image
Applications
Application Butylhydroxytoluene Ph Eur,JPE,NF,E 321. CAS 128-37-0, molar mass 220.35g/mol.
Physicochemical Information
Boiling point 265C (1013hPa)
Density 1.05g/cm3 (20C)
Flash point 127C
Ignition temperature 345C
Melting Point 69-70C
Vapor pressure 0.02hPa (20C)
Bulk density 450kg/m3
Solubility <0.001g/l
Toxicological Information
LD 50 oral LD50 Rat > 2000 mg/kg
Safety Information according to GHS
Hazard Pictogram(s)
Hazard Statement(s) H410: Very toxic to aquatic life with long lasting effects.
Precautionary Statement(s) P273: Avoid release to the environment.
RTECS GO7875000
Storage class 10 - 13 Other liquids and solids
WGK WGK 2 water endangering
Safety Information
Hazard Symbols Dangerous for the environment
Categories of danger dangerous for the environment
R Phrase R 50/53
Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
S Phrase S 61
Avoid release to the environment. Refer to special instructions/ Safety data sheets.
Storage and Shipping Information
Storage Store at +15C to +25C.
Transport Information
Declaration (railroad and road) ADR, RID UN 3077 , 9, III
Declaration (transport by air) IATA-DGR UN 3077 , 9, III
Declaration (transport by sea) IMDG-Code UN 3077 , 9, III, Marine Pollutant: P
Specifications
Assay (GC) 99.0%
Assay (HPLC) 99.0 - 101.5%
Identity (Identification 1 (JPE)) passes test
Identity (IR-spectrum) passes test
Identity (Identification 2 (JPE)) passes test
Identity (HPLC) passes test
Appearance White to yellowish crystalline powder.
Appearance of solution (100 g/l, methanol (Ph. Eur.)) Clear and not more intense in color than reference solutionY₅ or BY₅ (Ph. Eur.).
Appearance of solution (100 g/l, ethanol (95 )% (JPE)) Clear and colorless.
Solidification temperature 69.2 - 70.0C
Melting point 69.5 - 72.0C
Absorption maximum max.(ethanol abs.) 277 - 279nm
Spec. Absorptivity A 1%/1cm (max; 0.02 g/l; ethanol abs.) 81 - 88
Spec. Absorptivity A 1%/1cm (₂₇₈ nm; 0.05 g/l; ethanol (95 %)) 82 - 88
Heavy metals (as Pb) 10ppm
Sulphate (SO₄) 150ppm
As (Arsenic) 3ppm
Hg (Mercury) 1ppm
Pb (Lead) 2ppm
tert-butanol (GC) 1000ppm
Diisobutylene (GC) 100ppm
p-Cresol 0.1%
2-Propanol (GC) 2000ppm
Related substances (TLC) 0.5%
Related substances (HPLC) (p-Cresol oder m-cresol) 0.1%
Related substances (HPLC) (3-tert-Butyl-4-hydroxyanisole) 0.1%
Related substances (HPLC) (3,5-Di-tert-butyl-4-hydroxybenzoic acid) 0.1%
Related substances (HPLC) (2-tert-Butyl-4-methylphenol or 2-tert-butyl-5-methylphenol) 0.1%
Related substances (HPLC) (3,5-Di-tert-butyl-4-hydroxy benzaldehyde) 0.1%
Related substances (HPLC) (4,6-Di-tert-butyl-m-cresol) 0.1%
Related substances (HPLC) (2,6-Di-tert-butyl-phenol) 0.1%
Related substances (HPLC) (Any unspecified impurity) 0.1%
Related substances (HPLC) (Sum of all impurities) 0.7%
Other residual solvents (ICH Q3C) passes test
Sulfated ash (600 C) 0.002%
Water (according to Karl Fischer) 0.2%
Residues of metal catalysts or metal reagents acc. to EMEA/CHMP/SWP/4446/2000
are not likely to be present.
Corresponds to Ph. Eur., JPE, NF, E 321.
Conforms to the purity criteria on food additives according to the current European Commission Regulation.