109671 1,4-Dioxane
for analysis EMSURE® ACS,ISO
Product information
Grade
ACS,ISO
Synonyms
Glycolethylether, 1,4-Diethylene dioxide, 1,4-Dioxacyclohexane
Hill Formula
C4H8O2
HS Code
2932 99 00
EC number
204-661-8
Molar mass
88.11g/mol
EC index number
603-024-00-5
CAS number
123-91-1
Chemical and physical data
Ignition temperature
300C
Solubility
(20C)soluble
Saturation concentration (air)
149g/m3 (20C)Air
Melting point
12C
Molar mass
88.11g/mol
Density
1.03g/cm3 (20C)
pH value
6-8 (500g/l, H2O, 20C)
Boiling point
101.5C (1013hPa)
Vapor pressure
41hPa (20C)
Explosion limit
1.7-25.2%(V)
Flash point
11C
Evaporation number
7.3
Safety information according to GHS
Hazard Statement(s)
H225: Highly flammable liquid and vapour.
H351: Suspected of causing cancer.
H319: Causes serious eye irritation.
H335: May cause respiratory irritation.
EUH019: May form explosive peroxides.
EUH066: Repeated exposure may cause skin dryness or cracking.
Precautionary Statement(s)
P210: Keep away from heat/sparks/open flames/hot surfaces. - No smoking.
P281: Use personal protective equipment as required.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P308 + P313: IF exposed or concerned: Get medical advice/ attention.
Signal Word
Danger
Hazard Pictogram(s)
RTECS
JG8225000
Storage class
3 Flammable liquids
WGK
WGK 2 water endangering
Disposal
3
Relatively unreactive organic reagents should be collected in container A. If halogenated, they should be collected in container B. For solid residues use container C.
Safety information
R Phrase
R 11-19-36/37-40-66
Highly flammable.May form explosive peroxides.Irritating to eyes and respiratory system.Limited evidence of a carcinogenic effect.Repeated exposure may cause skin dryness or cracking.
S Phrase
S 9-16-36/37-46
Keep container in a well-ventilated place.Keep away from sources of ignition - No smoking.Wear suitable protective clothing and gloves.If swallowed, seek medical advice immediately and show this container or label.
Categories of danger
highly flammable, irritant, carcinogenic
Hazard Symbol
Flammable
Harmful
Transport information
Declaration (railroad and road) ADR, RID
UN 1165 Dioxan, 3, II
Declaration (transport by sea) IMDG-Code
UN 1165 DIOXANE, 3, II
Declaration (transport by air) IATA-DGR
UN 1165 DIOXANE, 3, II
Toxicological data
LD 50 oral
LD50 rat 5200 mg/kg
LD 50 dermal
LD50 rabbit 7600 mg/kg