متانول 106008 مرکMethanol 106008 merck
متانول 106008 مرک
Methanol 106008 merck
EMPROVE(r) ESSENTIAL Ph Eur,BP,JPE,NF
Description
Catalogue Number 106008
Synonyms MeOH, Hydroxymethane, Methyl alcohol, Carbinol
Product Information
CAS number 67-56-1
EC index number 603-001-00-X
EC number 200-659-6
Grade Ph Eur,BP,JPE,NF
Hill Formula CH₄O
Chemical formula CH₃OH
Molar Mass 32.04g/mol
HS Code 2905 11 00
Structure formula Image
Physicochemical Information
Boiling point 64.5C (1013hPa)
Density 0.792g/cm3 (20C)
Evaporation number 1.9
Explosion limit 5.5-44%(V)
Flash point 10C
Ignition temperature 455CDIN 51794
Melting Point -98C
Vapor pressure 128hPa (20C)
Toxicological Information
LD 50 oral LD50 Rat 5628 mg/kg
LD 50 dermal LD50 Rabbit 17100 mg/kg
Safety Information according to GHS
Hazard Pictogram(s)
Hazard Statement(s) H225: Highly flammable liquid and vapour.
H301 + H311 + H331: Toxic if swallowed, in contact with skin or if inhaled.
H370: Causes damage to organs.
Precautionary Statement(s) P210: Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
P240: Ground/bond container and receiving equipment.
P280: Wear protective gloves/ protective clothing.
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P308 + P310: IF exposed or concerned: immediately call a POISON CENTER or doctor/ physician.
P403 + P233: Store in a well-ventilated place. Keep container tightly closed.
RTECS PC1400000
Storage class 3 Flammable liquids
WGK WGK 1 slightly water endangering
Disposal 1
Strongly contaminated halogen-free organic solvents: container A.
Safety Information
Hazard Symbols Toxic
Flammable
Categories of danger highly flammable, toxic
R Phrase R 11-23/24/25-39/23/24/25
Highly flammable.Toxic by inhalation, in contact with skin and if swallowed.Toxic: danger of very serious irreversible effects through inhalation, in contact with skin and if swallowed.
S Phrase S 7-16-36/37-45
Keep container tightly closed.Keep away from sources of ignition - No smoking.Wear suitable protective clothing and gloves.In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).
Storage and Shipping Information
Storage Store at +5C to +30C.
Transport Information
Declaration (railroad and road) ADR, RID UN 1230 , 3 (6.1), II
Declaration (transport by air) IATA-DGR UN 1230 , 3 (6.1), II
Declaration (transport by sea) IMDG-Code UN 1230 , 3 (6.1), II
Specifications
Assay (GC) 99.5%
Identity (IR) conforms
Identity B (NF) conforms
Identity (JPE) conforms
Appearance conforms
Clarity of solution conforms
Acidity or alkalinity conforms
Acidity conforms
Alkalinity (as NH₃) 3ppm
Refractive index (n 20/D) 1.328 - 1.330
Density (d 20 C/20 C) 0.791 - 0.793
Boiling range (64-65C) 95% (v/v)
Absorbance (at 230 nm) 0.150
Absorbance (at 250 nm) 0.050
Absorbance (at 270 nm) 0.020
Absorbance (at 290 nm) 0.010
The absorption curve is smooth conforms
Benzene (impurity A) (GC) 2ppm
Acetone (GC) 0.001%
Ethanol (GC) 0.005%
Ethanol (JPE) conforms
Related substances (GC) conforms
Residual solvents class 3 (ICH Q3C) < 0.5
Other residual solvents (ICH Q3C) excluded by manufacturing process
Heavy metals conforms
Aldehydes and Acetone (as acetone) 0.003%
Aldehyde and other foreign reducing substances conforms
Reducing substances conforms
Readily oxidizable substances conforms
Readily carbonizable substances conforms
Readily carbonizable substances (JPE) conforms
Evaporation residue 0.0010%
Water 0.10%
Residues of metal catalysts or metal reagents acc. to EMEA/CHMP/SWP/4446/2000 are not likely to be present.
Conforms to Ph Eur, BP, JPE, NF