دی کلرو متان 106049 مرکDichloromethane 106049 merck
دی کلرو متان 106049 مرک
Dichloromethane 106049 merck
Description
Catalogue Number 106049
Synonyms DCM, Methylene chloride, Methylene dichloride
Description Dichloromethane
Product Information
CAS number 75-09-2
EC index number 602-004-00-3
EC number 200-838-9
Grade Ph Eur,BP,NF
Hill Formula CH₂Cl₂
Chemical formula CH₂Cl₂
Molar Mass 84.93g/mol
HS Code 2903 12 00
Structure formula Image
Physicochemical Information
Boiling point 40C (1013hPa)
Density 1.33g/cm3 (20C)
Evaporation number 1.9
Explosion limit 13-22%(V)
Ignition temperature 605CDIN 51794
Melting Point -95C
Vapor pressure 475hPa (20C)
Solubility 20g/l
Toxicological Information
LD 50 oral LD50 Rat 1600 mg/kg
LD 50 dermal LD50 Rat > 2000 mg/kg
Safety Information according to GHS
Hazard Pictogram(s)
Hazard Statement(s) H315: Causes skin irritation.
H319: Causes serious eye irritation.
H336: May cause drowsiness or dizziness.
H351: Suspected of causing cancer.
Precautionary Statement(s) P281: Use personal protective equipment as required.
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P308 + P313: IF exposed or concerned: Get medical advice/ attention.
RTECS PA8050000
Storage class 6.1 D Non combustible, acute toxicity cat. 3 / toxic or substances with chronic effects
WGK WGK 2 water endangering
Disposal 2
Organic halogenated solvents and solutions of organic halogen-containing substances: For strongly contaminated or mixed halogenated solvents container B: Caution: Do not use aluminium containers; in addition, in the case of water-containing chlorinated waste materials do not use stainless-steel containers (danger of leaks caused by corrosion).
Safety Information
Hazard Symbols Harmful
Categories of danger carcinogenic
R Phrase R 40
Limited evidence of a carcinogenic effect.
S Phrase S 3-36/37
Keep in a cool place.Wear suitable protective clothing and gloves.
Storage and Shipping Information
Storage Store at +15C to +25C.
Transport Information
Declaration (railroad and road) ADR, RID UN 1593 , 6.1, III
Declaration (transport by air) IATA-DGR UN 1593 , 6.1, III
Declaration (transport by sea) IMDG-Code UN 1593 , 6.1, III, Segregation Group: 10 (Liquid halogenated hydrocarbons)
Specifications
Purity (GC) 99.0%
Identity (IR) conforms
Appearance of the substance conforms
Acidic substances conforms
Acidity (HCl) 0.001%
Density (d 20 C/20 C) 1.320 - 1.332
Density (d 25 C/25 C) 1.318 - 1.322
Refractive index (n 20/D) 1.423 - 1.425
Free chlorine (Cl) conforms
Heavy metals (as Pb) 0.0001%
Ethanol,2-Methyl-2-butene and volatile impurities (GC) (Ethanol) 2.0% (v/v)
Ethanol,2-Methyl-2-butene and volatile impurities (GC) (2-Methyl-2-buten) 0.03% (v/v)
Ethanol,2-Methyl-2-butene and volatile impurities (GC) (Carbon tetrachloride (impurity A)) 0.001% (v/v)
Ethanol,2-Methyl-2-butene and volatile impurities (GC) (Chloroform (impurity B)) 0.005% (v/v)
Ethanol,2-Methyl-2-butene and volatile impurities (GC) (Total of impurities other than ethanol and 2-methyl-2-butene) 0.1% (v/v)
Ethanol,2-Methyl-2-butene and volatile impurities (GC)(reportingthreshold) 0.005% (v/v)
1,1-Dichloroethene (GC) 0.03%
1,2-Dichloroethene (GC) 0.03%
Other residual solvents (ICH Q3C) excluded by manufacturing process
Evaporation residue 0.002%
Water 0.020%
Residues of metal catalysts or metal reagents acc. to EMEA/CHMP/SWP/4446/2000 are not likely to be present.
The product is stabilized with about 50 ppm 2-Methyl-2-butene.
Conforms to Ph Eur, BP, NF